Ultraviolet Light for Disinfection
Ultraviolet light is an excellent choice for water disinfection. It is chemical free and
produces no harmful by-products. The application of UV to disinfect water has been an
accepted practice since the mid-20th century. It has been used primarily in medical
sanitation and sterile work facilities. Increasingly it is used to sterilize drinking and
beverage water, to purify water for microelectronics, and to disinfect wastewater.
Ultraviolet light is electromagnetic radiation with wavelengths shorter than visible
light shown in the chart. UV is separated into various ranges, with short range UV (UVC)
considered "germicidal UV." At the 254 nm wavelength UV is mutagenic to bacteria,
viruses and other microorganisms. UV will break the molecular bonds within the
microorganisms DNA, producing thymine dimmers, thereby destroying them, rendering
them harmless, or prohibiting growth and reproduction.
The effectiveness of germicidal UV depends on a number of factors: the length
of time a micro-organism is exposed to UV, power of the UV source at the 254 nm
wavelength, the presence of particles that can protect the microorganisms from UV,
and the microorganisms ability to withstand UV. Different species of microorganisms
require varying level of UV exposure to render them harmless, but nearly all species
can be reduced by 99.99% (4-log) with only a 30 mJ/cm2 dose of UV.
Using UV for TOC Reduction
Total oxidizable carbons (TOC) are increasingly finding their way into all our water supplies. Many TOC's are
carcinogens, such as dioxins, and others, like MTBE and endocrine disruptors, pose other serious health risks.
Removing or reducing TOC's in water is becoming increasingly necessary to ensure public health and safety.
UV radiation below 200 nm wavelengths can destroy TOC's in water through three different mechanisms. The
primary mechanism for TOC destruction is direct photolysis of the water molecules. This creates hydroxyl radicals
(chemical formula: OH-). The chemical equation is: H2O + UV (185 nm) H+ + OHHydroxyl
radicals are one of the most chemically reactive agents known. These radicals attack and oxidize the
organic chemicals, breaking them down into ionized organic species (which can be removed by deionization) and
eventually to CO2 and water, following the general formula: CxHyOz + OH- CO2 + H2O
A secondary mechanism by which UV radiation can destroy TOC's is by direct photolysis of the TOC molecule. The
UV photons break the chemical bonds within the TOC molecule, transforming it to two or more smaller organic molecules.
This process works only for organic chemicals which absorb light at the wavelengths produced by the UV source.
The third mechanism is the conversion of dissolved oxygen into first hydrogen peroxide, and then hydroxyl radicals,
by the 185 nm UV. The TOC destruction mechanism by hydroxyl ions is the same as above. The presence of dissolved
oxygen in the water is not guaranteed, and in some applications is actively prevented, but this process will occur if
dissolved oxygen is present.
Using UV for Chlorine Reduction
Using UV for de-chlorination eliminates the problems of traditional methods. There is no saturation point, no overdose
consideration, and no production of harmful or problematic by-products when using UV. Also, UV does not affect odor,
taste, or color or the pH of the water. In fact, the UV de-chlorination method enhances the end product quality and its
process stability.
An important point for consideration is that the UV dose for de-chlorination is significantly higher than used for typical
disinfection, anywhere from 10 to 20 times more. This higher dosage produces an extremely high level of microbial
disinfection in the water. As an added benefit, this dose will also reduce organic carbons such as Humic acid and
pesticides and trace pharmaceuticals. None of these advantages exist using the traditional chlorine reduction methods.
Why UVSI Reflector Technology Works
Typical UV water treatment systems suffer from inefficiency. Whether a low pressure or medium pressure system,
most of the UV light energy emitted is absorbed by the treatment chamber walls and is transformed into heat. Over 80%
of the UV photons are wasted this way, meaning less than 20% are doing the work of disinfection. This is a tremendous
loss of disinfection power. So reflecting the photons back into the water channel brings huge efficiency gains, resulting in
direct performance, size and cost benefits.
UVSI determined that three fundamental design conditions must be met to benefit from any reflective technology:
1. The material must be reflective across the UV spectrum from 180 nm to 300 nm.
2. The reflectivity of the material must be greater than 99% over this spectrum.
3. The water chamber must be enclosed to the maximum extent possible with the reflective material.
No UV design has satisfied all three conditions, until now. After two years of R & D, UVSI engineered a new UV treatment
chamber that meets all the conditions. The UVSI treatment chamber has a reflectivity factor greater than 99%. This
patented design "traps" the UV photons in the treatment chamber. They have no place to go other than into a microbe.
Ray trace modeling (figures below) shows the behavior of just 10 photons launched into the chamber. There are
hundreds of reflections per photon, creating a very uniform dose throughout the chamber, and numerous opportunities to
engage a microbe. With billions of photons active in this chamber, the gain in performance becomes geometric.
The amount of chamber coverage with the reflective material is fundamental in gaining performance. The chart
below illustrates that the chamber reflectivity must be greater than 98% to achieve meaningful performance gains.
UVSI products have a 20X gain in performance over competing systems, making UVSI products the most efficient,
the most compact, and the most economical UV systems available today.
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